Journal article
Nicole Kennedy, Peng Liu, Theodore Cohen
Angewandte Chemie International Edition, vol. 55, 2016, pp. 383-386
Angewandte Chemie International Edition, vol. 55, 2016, pp. 383-386
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APA
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Kennedy, N., Liu, P., & Cohen, T. (2016). 60. Fundamental Difference in Reductive Lithiations with Preformed Radical Anions versus Catalytic Aromatic Electron-Transfer Agents: N,N-Dimethylaniline as an Advantageous Catalyst. Angewandte Chemie International Edition, 55, 383–386. https://doi.org/10.1002/anie.201508971
Chicago/Turabian
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Kennedy, Nicole, Peng Liu, and Theodore Cohen. “60. Fundamental Difference in Reductive Lithiations with Preformed Radical Anions versus Catalytic Aromatic Electron-Transfer Agents: N,N-Dimethylaniline as an Advantageous Catalyst.” Angewandte Chemie International Edition 55 (2016): 383–386.
MLA
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Kennedy, Nicole, et al. “60. Fundamental Difference in Reductive Lithiations with Preformed Radical Anions versus Catalytic Aromatic Electron-Transfer Agents: N,N-Dimethylaniline as an Advantageous Catalyst.” Angewandte Chemie International Edition, vol. 55, 2016, pp. 383–86, doi:10.1002/anie.201508971.
BibTeX Click to copy
@article{kennedy2016a,
title = {60. Fundamental Difference in Reductive Lithiations with Preformed Radical Anions versus Catalytic Aromatic Electron-Transfer Agents: N,N-Dimethylaniline as an Advantageous Catalyst},
year = {2016},
journal = {Angewandte Chemie International Edition},
pages = {383-386},
volume = {55},
doi = {10.1002/anie.201508971},
author = {Kennedy, Nicole and Liu, Peng and Cohen, Theodore}
}
Surface deep: The reductive lithiation of phenyl thioethers proceeds by either preformed aromatic radical anions or by lithium metal and an aromatic electron-transfer catalyst. These two methods are fundamentally different: reductions with radical anions occur in solution, whereas the catalytic reaction occurs on the surface of lithium, which is constantly reactivated by the catalyst. A catalytic amount of N,N-dimethylaniline (DMA) and Li ribbon can achieve reductive lithiation.
